Treatment FAQ

how to optimize phosphorus removal in wastewater treatment process

by Kelli Hettinger Published 3 years ago Updated 2 years ago
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Strategies to optimize the wastewater phosphorus removal process

  • Biological phosphorus removal (BPR) and enhanced biological phosphorus removal (EBPR). Although the solids removal...
  • Chemical phosphorus removal (precipitation). Phosphorus precipitation involves dosing wastewater with metal salts, such...
  • Algal phosphorus removal. In this process, wastewater containing...

Full Answer

Does your wastewater treatment plant perform enough phosphorus removal?

Feb 16, 2022 · Strategies to optimize the wastewater phosphorus removal process Biological phosphorus removal (BPR) and enhanced biological phosphorus removal (EBPR). Although the solids removal... Chemical phosphorus removal (precipitation). Phosphorus precipitation involves dosing wastewater with metal salts, ...

How to reduce phosphorus concentration?

How to Optimize Your Phosphorus Removal Strategy. Effective and precise control of phosphorus can improve compliance and save money. It starts with smart application of phosphorus analyzers. Online analyzer measurements follow U.S. EPA and Standard Methods.

What is the best way to remove phosphate from wastewater?

Almost all wastewater treatment plants perform at least a secondary treatment, but this typically does not provide enough phosphorus removal. To meet the new requirements, facilities can do one of two things: 1) retrofit their plants to enhance biological treatment processes, or 2) add chemistry to help precipitate out the phosphate.

How low can phosphorus levels be in wastewater?

Jan 19, 2022 · Biological removal of phosphorus involves bacteria incorporating phosphorus into its cell biomass, helping to remove phosphorus in the process of sludge wasting. The reactor configuration provides the polyphosphate-accumulating organisms (PAO) with a unique benefit over other bacteria, encouraging PAO to grow and consume the phosphorus present.

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The principal advantages of biological phosphorous removal are reduced chemical costs and less sludge production as compared to chemical precipitation. In the biological removal of phosphorous, the phosphorous in the influent wastewater is incorporated into cell biomass, which is subsequently removed from the process as a result of sludge wasting.

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How do you remove phosphorus from wastewater?

Phosphorus removal from wastewater can be achieved either through chemical removal, advanced biological treatment or a combination of both. The chemical removal of phosphorus involves the addition of calcium, iron and aluminium salts to achieve phosphorus precipitation by various mechanisms which are discussed.

How is most wastewater phosphorus removed?

Chemical treatment is the most common method used for phosphorus removal to meet effluent concentrations below 1.0 mg/L.

How do you filter phosphorus from water?

Reverse Osmosis is one of the most common and effective methods used for treatment and removal of Phosphates in drinking water. A whole-house reverse osmosis system pushes water through a membrane with tiny pores. The membrane removes several contaminants, including Phosphate, while allowing water to pass through.Dec 15, 2020

How is phosphorus and nitrogen removed from wastewater?

Nitrogen and phosphorus removal from wastewater treatment plant effluent via bacterial sulfate reduction in an anoxic bioreactor packed with wood and iron.Sep 22, 2014

Why is removing phosphorus from wastewater important for the environment?

Phosphorus removal from wastewater is essential to ensure the safety and health of the public and protect the environment. Elevated levels of phosphorus can be hazardous to local animal life. Removing phosphorus from water can prevent eutrophication, which causes algae blooms.Jan 19, 2022

Why does excess phosphate need to be removed from wastewater?

The removal of phosphorus (P) from domestic wastewater is primarily to reduce the potential for eutrophication in receiving waters, and is mandated and common in many countries.Feb 22, 2018

Do water filters remove phosphorus?

Phosphates in water systems are removed chemically, biologically, or by using the biological-chemical method. In water filtration systems, granular activated carbon (GAC) removes phosphates in the drinking water.

Does RO remove phosphate?

Reverse Osmosis (RO) can treat swimming pool water with phosphates and the simple answer to this question is yes, RO can remove phosphates from pool water!Aug 7, 2017

How do you remove nitrates and phosphates from water?

Phosphate and nitrate pollutants can be removed by chemical precipitation, biological treatment, membrane processes, electrolytic treatment, ion-exchange and adsorption process to remove these pollutants from water sources effectively.Dec 24, 2016

Is nitrification aerobic or anaerobic?

Nitrification is an important step in the nitrogen cycle in soil. Nitrification is an aerobic process performed by small groups of autotrophic bacteria and archaea.

Which chemicals are commonly used to remove phosphate from wastewater?

Chemical phosphorus removal typically involves precipitating influent phosphorus with an iron or aluminum salt. Using an iron salt, such as ferric chloride, provides the ancillary benefits of reducing scum in secondary treatment and managing sulfides and odors in anaerobically digested sludge.Sep 13, 2018

Why is Ammonification necessary?

Ammonification of organic nitrogen is an important processes in water because biological assimilation of ammonium by bacteria, biofilms, and aquatic plants is preferred to nitrate assimilation.Jan 1, 2008

Why is it important to lower phosphate levels in wastewater?

The benefit of using a chemical treatment to lower phosphate levels in wastewater is that it can provide immediate results without the wait for construction (of a physical solution). However, traditional chemical treatments can add significant sludge removal costs; these costs can be especially extreme if the method used is the application ...

How low is phosphorus in the US?

Some states are contemplating switching to new, more stringent standards—in some cases as low as 0.1 mg/L. That’s ten times lower than the current standard.

How to nitrify and denitrify wastewater?

One approach that works well to nitrify and denitrify wastewater is to retrofit existing wastewater plants with particulate phosphorus membrane technologies; however, this method may lack the intended benefit of phosphate removal. Furthermore, due to the high capital cost of investment required upfront, it may take years to see a return on investment. Over the long term, however, this process can be a cost-effective solution to reduce phosphate levels.

Where is phosphorus found?

Phosphorus is found in almost every fertilizer that is manufactured commercially. After crops are fertilized, the excess nutrients in the fertilizer, like phosphorous, are washed into our watershed.

Is phosphorus in wastewater strict?

As phosphorus issues persist, regulations that limit levels in wastewater will become more strict. For many treatment facilities, understanding how to effectively remove phosphorus from their effluent might be a challenge, but it is surely possible.

Does phosphate cause eutrophication?

The issue is, phosphate also promotes eutrophication— the growth of aquatic plants in bodies of water, which includes harmful algal blooms (cyanobacteria). These cyanoHABs can produce noxious toxins that are harmful to both humans and animals.

Can wastewater plants remove phosphorus?

Almost all wastewater treatment plants perform at least a secondary treatment, but this typically does not provide enough phosphorus removal. To meet the new requirements, facilities can do one of two things: 1) retrofit their plants to enhance biological treatment processes, or 2) add chemistry to help precipitate out the phosphate.

Why Is Phosphorus a Problem in Wastewater?

While phosphorus is a necessary element, high levels of phosphorus can lead to multiple environmental complications in streams, lakes, rivers and coastal areas. A typical issue caused by elevated phosphorous in natural water sources is Eutrophication – a rampant stimulation of algae and other plants, leading to oxygen depletion in the water.

How Should Phosphorus be Removed from Wastewater?

There are several forms of phosphorus removal, the most effect effective system will depend on the characteristics of the wastewater, the existing infrastructure at treatment facility, and the effluent phosphorous level required. Project budget, operator maintenance, and form of phosphorous should also be taken into consideration.

Chemical vs. Biological Phosphorus Removal

Chemical phosphorus removal uses precipitating phosphors with an aluminum salt or iron salt. Iron salt, including ferric chloride, can provide numerous benefits to reduce scum in secondary treatment processes and manage orders and sulfides in anaerobically digest sludge.

Chemical Phosphorus Removal

Chemical phosphorus removal is a wastewater treatment process that uses iron, calcium or aluminum salts to remove phosphorus from the water. Phosphates create precipitates with metal ions and are removed with sludge in the separation unit.

Chemical System Options

There are numerous chemical systems that can remove phosphorus from water, including chemical dosing to promote p-precipitation, absorptive media for p-removal and ion exchange technologies.

Biological Phosphorus Removal

Biological phosphorus removal is a wastewater treatment process used to remove phosphorus from water. Biological phosphorus removal implementations use a group of heterotrophic bacteria to process excess phosphorus levels from water. Some of the main pros and cons of biological phosphorus removal include:

Biological System Options

Some of the most common biological system options include identification of PAO, metabolism of PAO, traditional enhanced biological phosphorus removal (EBPR), novel EBPR systems and potential EBPR systems.

How is phosphorous removed from wastewater?

In the biological removal of phosphorous, the phosphorous in the influent wastewater is incorporated into cell biomass, which is subsequently removed from the process as a result of sludge wasting. The reactor configuration provides the P accumulating organisms (PAO) with a competitive advantage over other bacteria. So PAO are encouraged to grow and consume phosphorous. The reactor configuration in comprised of an anaerobic tank and an activated sludge activated tank. The retention time in the anaerobic tank is about 0.50 to 1.00 hours and its contents are mixed to provide contact with the return activated sludge and influent wastewater.

What is the process of removing phosphorus from wastewater?

The removal of phosphorous from wastewater involves the incorporation of phosphate into TSS and the subsequent removal from these solids. Phosphorous can be incorporated into either biological solids (e.g. micro organisms) or chemical precipitates.

How is the amount of phosphorous removed by biological storage estimated?

The amount of phosphorous removed by biological storage can be estimated from the amount of bsCOD that is available in the wastewater influent. Better performance for BPR systems is achieved when bsCOD acetate is available at a steady rate.

What is the chemical precipitation of phosphate?

Chemical precipitation is used to remove the inorganic forms of phosphate by the addition of a coagulant and a mixing of wastewater and coagulant. The multivalent metal ions most commonly used are calcium, aluminium and iron. Calcium: it is usually added in the form of lime Ca (OH) 2.

What are the processes of phosphate removal?

The main phosphate removal processes are (see picture below): 1 Treatment of raw/primary wastewater 2 Treatment of final effluent of biological plants (postprecipitation) 3 Treatment contemporary to the secondary biologic reaction (co-precipitation).

What is the difference between orthophosphate and polyphosphate?

Usually polyphosphates undergo hydrolysis and revert to the orthophosphate forms.

How much phosphorus is discharged from a water treatment?

Normally secondary treatment can only remove 1-2 mg/l, so a large excess of phosphorous is discharged in the final effluent, causing eutrophication in surface waters. New legislation requires a maximum concentration of P discharges into sensitive water of 2 mg/l.

How low is phosphorus in wastewater?

A number of water quality studies in Northwest states have determined waste load allocations which will require dischargers to achieve total phosphorus effluent concentrations that range from as low as 0.009 to 0.05 mg/l. Even as WWTP operators in the Northwest consider installing additional treatments to address water quality problem, they are also planning to upgrade capacity of their plants to accommodate rapid population growth. With many other interests competing for limited public and private resources, resolving water quality problems is often contentious and slow. Implementation of water quality improvement plans (called Total Maximum Daily Loads (TMDLs)) have been significantly delayed by arguments about the availability and cost of treatment technologies capable of achieving very low phosphorus targets.

How much phosphorus is in a plant effluent?

No chemicals are currently used at the plant to enhance phosphorus removal. Nevertheless, the final effluent typically contains between only 0.1 to 0.2 mg/l total phosphorus. Influent BOD and ammonia nitrogen were reported to be approximately 200 to 300 mg/l and 30 mg/l, respectively. Effluent BOD concentrations average about 2.2 mg/l and ammonia nitrogen is less than 0.1 mg/l.

What are the phosphorus limitations for WWTPs?

The lowest phosphorus limitation established for any of these WWTPs was a monthly average limitation of 0.05 mg/l. Operators at many of these WWTPs conveyed that if necessary, even better phosphorus removal performance could be achieved through operational changes to the existing treatment system. This is a consideration that should not be overlooked by dischargers, consultants and regulators as they consider treatment options.

How does phosphorus affect freshwater?

In freshwater systems, phosphorus is typically the nutrient that is in short supply relative to biological needs, which means that the productivity of aquatic plans and algae can be controlled by limiting the amount of phosphorus entering the water. Many streams and lakes in the Northwest are documented to have very little capacity to assimilate phosphorus loading during the “critical” warm and dry summer period without significant water quality degradation. Large diurnal swings in pH and dissolved oxygen may occur as excessive amounts of nutrients are metabolized by aquatic plants and algae. The range of these swings is often measured to exceed the state water quality criteria established to protect fish and other aquatic organisms in their various life stages. Therefore, the amount of phosphorus currently entering these waters exceeds the seasonal loading capacity and must be reduced if these water quality problems are to be resolved.

What is the most significant source of phosphorus?

agriculture, pet waste) is often minimal during the summer months because there is typically very little rainfall runoff to flush pollutants into receiving waters. The discharges of treated wastewater can be the most significant source of phosphorus loading during these critical summer months. To address these water quality problems, state environmental agencies and the Environmental Protection Agency (EPA) are requiring dischargers to reduce the amount of phosphorus in their effluent.

Why are WWTPs selected?

The WWTPs included in this project were selected because monitoring results have demonstrated their treatment to be very effective at removing phosphorus. The reported performance at each of these facilities has been well documented by monitoring conducted over periods of several years. EPA attempted to include a variety of treatment technologies and facilities of different sizes in this evaluation. However, not all facilities that achieve exemplary phosphorus removal nor all filtration technologies could be presented in this report. A number of the WWTPs that are currently achieving good phosphorus removal are planning treatment upgrades that will allow them to also meet a total nitrogen limitation of 3 mg/l. Some information about treatment to remove nitrogen is presented in the description of the LOTT, Budd Inlet WWTP.

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