Treatment FAQ

what was the purpose of the pre-treatment in biodiesel

by Waino Ward Published 2 years ago Updated 2 years ago
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Converting waste oils/fat into biodiesel using alkaline catalyst is difficult, as it contains more than one percent Free Fatty Acid (FFA) which will form soap during the transesterification process. Hence, it is desirable to reduce the level of FFA lower than one percent for biodiesel production using the pre-treatment process.

What is “Pretreatment” and why is it needed? Pretreatment describes any and all steps required to prepare feedstock for transesterification. This most commonly involves water removal and converting FFA into useable oil.

Full Answer

What is pure biodiesel used for?

Metrolink has announced that it is switching to renewable fuel making it the first in the US to completely power all its locomotives ...

What is the process of preparing biodiesel?

cannot be processed through any biodiesel producing equipment. The proposed idea is to design a device that will separate the desired oil from the water and debris. Acting as a pre-cleaning station, the design will allow biodiesel companies to purchase impure oil, purify it using the system and finally, run it through their plant. The main

What are the unit operations involved in biodiesel production?

Feb 01, 2011 · A pulsed-electric-field (PEF) pre-treatment technology to facilitate extraction of oils from algae cells was introduced recently by Diversified Technologies Inc. (Bedford, Mass.; www.divtecs.com). Algae have drawn considerable interest as a renewable source of biofuels, but the costs of algae-derived fuels remain much higher than petroleum-derived fuels.

Why is biodiesel becoming so popular?

Proposed Pre-treatment Plant (www.ageratec.com) Integrate a WVO pretreatment station into Biodiesel plant in order to reduce significantly water and bio-solids while meeting our client’s requirements. Implement low energy consuming components and strategies such as oil & water separator and fluid stagnation system.

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What is pretreatment process in biodiesel?

Biodiesel pretreatment is the process of taking the crude oil extracted from the back end of a dry-grind ethanol process and making it suitable for use in a biodiesel plant. The extracted corn oil from the back end of an ethanol plant is usually high in free fatty acids (FFA).

What is the purpose of the biodiesel experiment?

A simple and quick chemical experiment of biodiesel synthesis for high school students is described. This experiment is helpful for high school students to understand transesterification, catalysis, esters, alcohols, and biodiesel.Sep 11, 2013

What are the feedstocks for biodiesel?

Rapeseed oil, sunflower oil, and palm oil are major feedstocks for biodiesel production in other countries. Algae are potential sources for biofuels.Feb 10, 2022

What is FFA in biodiesel?

Currently, most of the biodiesel is produced from the refined/edible type oils using methanol and an alkaline catalyst. However, large amount of non-edible type oils and fats are available. The difficulty with alkaline-esterification of these oils is that they often contain large amounts of free fatty acids (FFA).

What molecules does the aqueous layer Remove from the biodiesel?

Discard the bottom, aqueous layer into the labeled waste container. Repeat the extraction step using 1 mL of distilled water. The extraction or “washing” in step 3 removes flammable ethanol, glycerol byproduct, catalyst, and fatty acid salts (“soaps”) from your biodiesel.

Why Methanol is used in biodiesel production?

Methanol and ethanol are the most often used alcohols in biodiesel production. Methanol is particularly preferred because of its physical and chemical advantages. Beside its reaction with triglycerides is quick and it can be easily dissolved in NaOH [57].

What are feedstocks used for?

Feedstock is raw material used for processing or manufacturing another product. Examples of feedstock include crude oil, which is used to produce gasoline, corn, which is used to produce ethanol, and soybean oil, which is used to produce biodiesel.

What is the process of transesterification?

Transesterification is the process in which fat or oil reacts with an alcohol to form esters and glycerol. A catalyst is used to improve the reaction rate and yield. Because the reaction is reversible, excess alcohol is used to shift the equilibrium to the product side.Jul 7, 2007

What are the feedstocks for energy production?

A feedstock is defined as any renewable, biological material that can be used directly as a fuel, or converted to another form of fuel or energy product.
...
Feedstocks
  • Biofuel.
  • Biodiesel Production.
  • Gasification.
  • Pyrolysis.
  • Biodiesel.
  • Bio-Oil.
  • Biomass.
  • Hydrogen.

How is FFA removed from biodiesel?

Two methods exist for removing FFA from feedstock:
  1. Caustic Stripping. Caustic is used to “strip” FFA from oils. ...
  2. Acid Esterification. Methanol and sulfuric acid are mixed with oils, and FFA is converted into methyl esters.

How can production of free fatty acids impact Biodiesel Production?

However, the high free fatty acids (FFA) content in waste cooking oils can greatly reduce the efficiency of the alkali-catalyzed transesterification reaction that is most commonly used in making biodiesel.Mar 26, 2018

How can the presence of free fatty acids impact Biodiesel Production?

Studies show that the presence of water or Free Fatty Acids (FFA) acts as poison for the catalyst. Second, the price of pure triglyceride does not allow biodiesel to compete with diesel fuel in cost [4, 5].

1. What is Biodiesel Fuel?

Ans. To define biofuel, it can be said to be a naturally obtained fuel which is produced from animal fats and vegetable oils mixed with alcohol.

2 What are the Essential Features of Biodiesel?

Ans. The essential features of biodiesel are - clean fuel, eco-friendliness, user-friendly, non-toxic, non-polluting, danger-free, heating agent, l...

3. What are the Benefits of Biodiesel?

Ans. Biodiesel is a naturally produced fuel consisting of natural constituents - vegetable oils or animal fats. So, it does not pollute the environ...

What is the process of preparing biodiesel?

The process of preparing biodiesel is termed as transesterification. One of the top applications of biodiesel is as a heating fuel. We can mix biodiesel with petroleum during its production to increase efficiency. For more information on what is biodiesel, you can look into our online learning programs.

What are the benefits of biodiesel?

Other benefits of biodiesel include its user-friendliness. You do not have to modify the engines for using it.

What is biodiesel made of?

Biodiesel - Production, Advantages, Uses and FAQ. Biodiesel. Biology. Biodiesel. Biodiesel is a fuel source that is obtained from animal fats and vegetable oils. It is a renewable source of energy and hence is widely researched to increase its efficiency and advantages. Owing to the intensive search for non-conventional sources of energy, ...

What is biofuel?

Ans. To define biofuel, it can be said to be a naturally obtained fuel which is produced from animal fats and vegetable oils mixed with alcohol.

Why are students unaware of biodiesel?

Students are often unaware about what is biodiesel because unlike solar or wind energy, this energy resource is not that popular . While it is vital to understand this type of fuel, students should begin by noting that it comes with specific advantages. Understandably, it is gaining in it popularity.

Does biodiesel pollute the environment?

Ans. Biodiesel is a naturally produced fuel consisting of natural constituents - vegetable oils or animal fats. So, it does not pollute the environment and keeps the surrounding clean. Share this with your friends.

Is biodiesel a non-biodegradable source of energy?

Biodiesel can be used as a fuel in the …………… of automobiles as an alternative for petroleum diesel. Biodiesel is a non-biodegradable source of energy. Biodiesel contributes to environmental pollution.

When was biodiesel first used?

History of biodiesel. Before petroleum diesel fuel became popular, Rudolf Diesel, the inventor of the diesel engine in 1897, experimented with using vegetable oil (biodiesel) as fuel. Until 2001, the United States consumed only small amounts of biodiesel.

Why is biodiesel called biodiesel?

It is called biodiesel because it is mostly used in diesel engines. Pure biodiesel (B100) can also be used in many applications. Petroleum diesel fuel tanks and equipment can also store and transport biodiesel. Learn more about use of biodiesel made from different feedstocks. Biodiesel blends may also be used as heating oil.

Why are biomass fuels called biomass fuels?

They are both called biomass-based diesel fuels because they are mostly produced for use in diesel engines, but they can also be used as heating fuels. Both fuels are made from biomass or materials derived from biomass, but they differ in how they are produced and in their physical properties. Biodiesel meets the American Society for Testing ...

What is biodiesel made of?

Biodiesel can be made from nearly any feedstock (raw material) that contains adequate free fatty acids. Most of U.S. biodiesel production uses raw vegetable oils, used cooking oils, yellow grease, and animal fats as feedstocks for transesterification.

What are the main feedstocks for biodiesel?

Rapeseed oil, sunflower oil, and palm oil are major feedstocks for biodiesel production in other countries. Algae is also a potential source for biodiesel production. Algae contain fat pockets that help keep them afloat. This fat can be collected and processed into biodiesel.

How much biodiesel is produced in the US?

In 2019, the United States produced about 41 million barrels (1.7 billion gallons) of B100, ...

Does renewable diesel need to be blended?

Renewable diesel meets ASTM D975 specification for petroleum diesel, and it does not require blending with petroleum diesel for its use. Both fuels qualify for meeting the biofuels consumption levels required by the U.S. Renewable Fuel Standard Program.

What is the process of making biodiesel?

Figure 1 shows a schematic diagram of the unit operations involved in biodiesel production. Depending on the quality of the feedstock, either esterification or transesterification reactions are used for biodiesel production (see FAPC Fact Sheet FAPC-149 Biodiesel Glossary for definition of the terms). Most of the current biodiesel production operations use base catalysis (transesterification). This method works well if the free fatty acid, moisture and phosphorous contents of oil/fat are less than 0.1 percent, less than 0.1 percent and less than 10 ppm, respectively. Typical feedstocks for biodiesel production are soybean, canola/rapeseed, sunflower, cottonseed, palm seed and palm kernel, corn and mustard seed oil. Pork, beef and poultry fat and grease also can be converted to biodiesel. Palm oil and animal fat may have a high free fatty acid content, which causes soap formation that has adverse effects on downstream processing and leads to yield reduction.

How to convert oils to biodiesel?

Fats and oils with high free fatty acid content can be converted to biodiesel using acid catalysis, which is the second approach for handling high free fatty acid content feedstock. This technique uses a strong acid. Soap formation is not a problem because there are no alkali metals in the reaction medium. Acid catalysts can be used for transesterification of the triglycerides, but the reaction might take several days to complete. This is too slow for industrial processing.

How to remove free fatty acids from feedstock?

One way would be to refine the feedstock before base catalysis. Free fatty acids can be removed by chemical neutralization or physical deacidification. Chemical neutralization involves treatment with caustic NaOH or KOH. Soap formed during this process is removed, and the remaining oil is ready for base catalysis. However, some oil is lost during this process. Physical deacidification, or steam stripping, also removes free fatty acids. This process is performed under vacuum and requires steam.

What is the most common catalyst for transesterification?

Sodium hydroxide (NaOH), potassium hydroxide (KOH) and sodium methoxide (CH 3 ONa) are the most common catalysts for transesterification. Sodium methylate (sodium methoxide) is more effective than NaOH and KOH as a catalyst, but it is more expensive.

Is methanol a biodiesel?

Methanol is the most common alcohol used for conversion of fats and oils to biodiesel. Methanol is flammable, so proper handling is required for safety. Detailed information on methanol and biodiesel handling can be found at Biodiesel Community . Transesterification is a reversible reaction.

Is transesterification continuous or batch?

Both transesterification and esterification reactions can be operated either as a batch or continuous process. A batch process is better suited to smaller plants that produce less than 1 million gallons per year and provide operation flexibility. Continuous processing allows use of high-volume separation systems, and therefore increases throughput.

Can pork fat be converted to biodiesel?

Pork , beef and poultry fat and grease also can be converted to biodiesel. Palm oil and animal fat may have a high free fatty acid content, which causes soap formation that has adverse effects on downstream processing and leads to yield reduction.

How is biodiesel made?

Both glycerol and biodiesel need to have alcohol removed and recycled in the process. Water is added to both the biodiesel and glycerol to remove unwanted side products, particularly glycerol, that may remain in the biodiesel. The wash water is separated out similar to solvent extraction (it contains some glycerol), and the trace water is evaporated out of the biodiesel. Acid is added to the glycerol in order to provide neutralized glycerol.

How much alcohol is needed to make biodiesel?

The amount of methanol added is almost double the required amount so the reaction goes to completion. With 100 lbs of fat and 16-20 lbs of alcohol (and 1 lb of catalyst), the reaction will produce 100 lbs of biodiesel and 10 lbs of glycerin. The reaction typically takes place at between 40-65°C. As the reaction temperature goes higher, the rate of reaction will increase, typically 1-2 hours at 60 °C versus 2-4 hours at 40°C. If the reaction is higher than 65°C, a pressure vessel is required because methanol will boil at 65°C. It also helps to increase the methanol to oil ratio. Doubling the ratio of 3 mols of alcohol to 6 mols will push the reaction to completion faster and more completely.

What is the first step in the transesterification process?

The first step is to mix the alcohol for reaction with the catalyst, typically a strong base such as NaOH or KOH. The alcohol/catalyst is then reacted with the fatty acid so that the transesterification reaction takes place. ...

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