Treatment FAQ

why does increasing time for a heat treatment lower recrystallization temperature

by Jace Larson Published 3 years ago Updated 2 years ago

By increasing the cold working temperature, we lower the internal energy, and thus increasing the amount of energy (due to heat) required to reach the energy needed for recrystallization to take place. Thanks to you and this explanation, I believe I understand this better.

Full Answer

How does temperature affect the rate of recrystallization?

By increasing the cold working temperature, we lower the internal energy, and thus increasing the amount of energy (due to heat) required to reach the energy needed for recrystallization to take place. Thanks to you and this explanation, I believe I understand this better.

What is the temperature for recrystallization of aluminum?

Cold-worked aluminum alloys get strain hardness, requiring that the material is annealed. The recrystallization temperature of alloys may vary from 340° to 400°C (650° to 750°F). The temperature and the rate of heating are specific to the alloy and must be carefully applied.

Can cold work cause recrystallization?

Below this amount of cold working, no recrystallization can occur. When a material is subject to cold working, the energy is converted into heat while a small portion causes defects (dislocations). The more the number of defects, the greater the tendency to recrystallise.

What is the difference between recrystallization and homogenization?

Recrystallization temperatures are generally a bit lower than homogenization temperatures because there is no macroscopic diffusion required, as opposed to the homogenization process. They also depend on the cold-working: the more important the cold-working, the lower the recrystallization temperature.

How does time affect recrystallization?

Increasing annealing time decreases recrystallization temperature. Alloys have higher recrystallization temperatures than pure metals. Increasing amount of cold work decreases recrystallization temperature.

What is the recrystallization temperature and how is it affected by longer annealing times?

It can be seen that with the increase of annealing time and annealing temperature, the volume fraction of recrystallization increases to more than 60%, and the large deformation grains almost disappear. After annealing at 430 °C for 8 h, the deformed grains are basically transformed into small recrystallized grains.

What increases recrystallization temperature?

Arsenic, in amounts up to 0.5%, may be added to copper to increase recrystallization temperature and increase high temperature strength. Lead, in amounts up to approximately 2.0%, may be added to copper to improve machinability.

What does recrystallization temperature depend on?

The recrystallisation conditions, such as heating rate and soaking time depend on the degree of cold work and the steel composition. The rate of softening increases rapidly as the annealing temperature reaches A1 point.

Is there a relationship between recrystallization temperature and annealing times briefly explain your answer?

The recrystallization temperature is not a constant for a material but depends on the amount of cold work, the annealing time, and other factors. At this temperature atomic mobility becomes high enough to allow recrystallization.

What happens during recrystallization in annealing?

During a recrystallization anneal, new grains form in a cold-worked metal. These new grains have a greatly reduced number of dislocations compared to the cold-worked metal. This change returns the metal to its pre-cold-worked state, with lower strength and increased ductility.

Why does increased cold work lower recrystallization temperature?

Increasing the amount of cold work increases both the nucleation rate and growth rate, which effectively lowers the recrystallization temperature. However, since the increase in nucleation rate is greater than growth rate, larger amounts of cold work produce finer grain sizes during recrystallization.

What are five important factors that affect the recrystallization process in metals?

Some factors such as temperature, extent and complexity of deformation, grain size, melting point and purity of metallic materials, presence of foreign atoms and second phase particles, stacking fault energies and crystallographic texture which affect stored energy of deformation are well known to influence the primary ...

What is the relationship between recrystallization temperature and percentage cold work?

Increased deformation (cold work) leads to a decrease in recrystallization temperature (Trx). If the initial grain size is smaller then the recrystallization temperature is lower. Higher amount of cold work + low initial grain size leads to finer recrystallized grains.

Does recrystallization increase melting point?

By applying the technique of recrystallization or sublimation, the purity of a substance can be increased, and its corresponding melting point range will become smaller.

Is recrystallization temperature the same as melting temperature?

Recrystallization temperature is typically one-third to one-half the melting point (in degrees Kelvin), and raises the atomic mobility, which results in recrystallization. The recrystallization results in lower hardness and strength properties of the material, in addition to increased ductility.

What causes impurities in recrystallization?

After the solvent evaporates, the crystals that are left behind can serve as seeds for further crystallization. Both these methods of nucleation (i.e. etching and seed crystals) cause very rapid crystallization, which can lead to the formation of impure crystals.

Why is recrystallization temperature lower than homogenization temperature?

Recrystallization temperatures are generally a bit lower than homogenization temperatures because there is no macroscopic diffusion required, as opposed to the homogenization process . They also depend on the cold-working: the more important the cold-working, the lower the recrystallization temperature.

What is solution heat treatment?

Also called quenching, solution heat treatment involves cooling the copper products after forming by immersion in a continuous flow bath, or by spraying. Water is normally used. An exception is the quenching of products formed by extension, in which case an oil and water solution is normally used.

What are the nucleation sites of austenite to ferrite?

In clean steels, the most relevant nucleation sites for the austenite-to-ferrite transformation are the austenite grain boundaries. In the case of transformation in deformed austenite, dislocation bands within the grains can also act as nucleation sites.

What is hot strip rolling?

In hot strip rolling, a slab, usually a steel stock heated above the recrystallization temperature, is passed through the roll gap several times, with the gap being progressively reduced to achieve the desired final dimensions . Mill designers and operators are keenly interested in proper design and control of the hot strip rolling precess. The specific goals to be achieved by process design and control may vary depending on the need of the manufacturers and customers, but product quality as well as production economy is a fundamental consideration in most cases.

How does annealing work?

Annealing involves heating the copper or copper alloy, often by the combustion of natural gas, for the purpose of reducing stresses introduced into the metal by forging or cold rolling. “Electroneal” units work by passing electrical current through the formed wire.

What temperature does aluminum have to be to be annealed?

The recrystallization temperature of alloys may vary from 340 to 400°C (650 to 750°F) the temperature and the rate of heating is specific to the alloy and must be carefully applied.

What is cold rolling?

Like hot rolling, cold rolling involves passing the metal between a series of rollers, some of which are opposite others, in such a way as to make this cross-section of the metal piece become ever smaller. Since cold rolling is done at temperatures below the recrystallization temperature, the product is less ductile.

What causes recrystallization at lower temperatures?

As the degree of cold work increases, the recrystallization occurs at lower temperatures and in shorter times. This is also affected by the fact that there is more strain in the lattice structure, the grains are of a smaller size. Other factors affect the recrystallization temperature such as the deformation temperature, original grain size, ...

What is the minimum deformation required for recrystallization?

For recrystallization to occur, the material must be subject to a minimum deformation called the deformation threshold. Below this amount of cold working, no recrystallization can occur. When a material is subject to cold working, the energy is converted into heat while a small portion causes defects (dislocations).

Why does attraction force decrease as temp increases?

Since as temp increases the molecules get further from each other as because addition of heat means addition of energy ; more velocity of molecules ie ; more kinetic energy. So attraction force between same kind of molecules decreases (cohesive force) as because they ar now at a distance from each other .

Why does the temperature of the Earth decrease with height?

The reason for this phenomenon is that the air becomes thin as we go higher up. The earth is surrounded by an envelope of gas called the atmosphere which is held in place by earth's gravity.

How much of the atmosphere absorbs infrared radiation?

The absorption of infrared is a limited process because only 2% of atmosphere can absorb radiation. Of this 2% water vapour is responsible for 99% of infrared absorption. The remaining 98% of atmosphere (oxygen, nitrogen and argon) only absorb heat by conduction. This is largely happening at the bottom of atmosphere.

How does the Earth get its heat?

It gets the bulk of its heat from earth’s surface by conduction and absorbing long wave radiation. Conduction is a slow process because air has low thermal conductivity and it becomes less dense as you go up. The absorption of infrared is a limited process because only 2% of atmosphere can absorb radiation.

Why does gravity increase the density of the atmosphere?

Because of gravity atmosphere has weight per height of mass. Both pressure and temperature are functions of the same statistical expressions: number of collisions with unit surface area per unit of time. As you go down in atmosphere the density increases, which means number of collisions will increase.

Why would a heat treater use a heat treating temperature that is too high or too low?

So, why might a heat treater use a heat treating temperature that is too high or too low? To save money, to save time, or just sloppy. To reduce energy costs a heat treater might try to run its furnaces at the low end of the required temperature range.

What happens when you use too low temperature?

Using a temperature that is too low can result in incomplete metallurgical transformations, cold worked metals that do not soften sufficiently, or insufficient stress relief. For example, during the through hardening heat treatment of a carbon steel, the steel is heated to transform all the ferrite and cementite to austenite ...

What happens if you don't heat steel?

If the steel is not heated to a high enough temperature, then there is the risk that all the ferrite and cementite does not transform to austenite. If this occurs, then when the steel is quenched, the remaining ferrite and cementite will be present along with the martensite.

What happens if you anneal metal?

If the annealing temperature is too high, then excessive grain growth will occur. This will result in the metal having lower strength and hardness than intended. Also, if the metal is to be formed, there is the risk of orange peel, a cosmetic defect in heavily formed metals with grains that are too large. So, why might a heat treater use ...

How does natural pressure affect recrystallization?

This increased pressure can change the baseline of recrystallization at a lower temperature. It can also be altered by alloying elements up or down. Best wishes. Cite.

What is the energy needed to recrystallize?

The energy needed to recrystallize is the internal energy introduced by cold working plus the energy supplied by heat. By increasing the cold working temperature, we lower the internal energy, and thus increasing the amount of energy (due to heat) required to reach the energy needed for recrystallization to take place.

How does heating affect the treatment of steel?

The treatment of steels is strongly influenced by the heating temperature. Heating to the crystallization line leads to structural changes. These changes alter the mechanical and technological properties of the steel bits, reducing the mechanical strength, and increasing plasticity.

Does cold deformation increase recrystallization temperature?

In short: cold deformation at an increased temperature would yield an increased recrystallization temperature. This reasoning can only be considered as a zero approach as the eventual effects of secondary phases and/or interstitials (carbon and nitrogen) are not taken into account.

What is heat treatment?

Heat treatment is the process of heating metal without letting it reach its molten, or melting, stage, and then cooling the metal in a controlled way to select desired mechanical properties. Heat treatment is used to either make metal stronger or more malleable, more resistant to abrasion or more ductile.

Why do you need to heat parts slowly?

Larger parts or parts with uneven cross sections need to be heated more slowly than small parts to allow the inside temperature to be close to the surface temperature. Otherwise, there’s a risk of cracking or excessive warping.

What happens when you heat metal?

All of the typical processes performed on metals produce heat, whether it’s welding or cutting, and any time you heat metal, you change the metallurgical structure and properties of it. Inversely, you can also use heat treatment to restore metals to its original form.

How to determine the soaking period of a metal?

To determine the correct length of time, you will need the chemical analysis and mass of the metal. For uneven cross-sections, you can determine the soaking period using the largest section.

What is the cooling stage of metal?

The Cooling Stage. In the cooling stage, you’ll want to cool metal back to room temperature, but there are different ways to do this depending on the type of metal. It may need a cooling medium, a gas, liquid, solid, or combination thereof. The rate of cooling depends on the metal itself and the medium for cooling.

How many stages of heat treatment?

Stages of Heat Treatment. There are three stages of heat treatment: Heat the metal slowly to ensure that the metal maintains a uniform temperature. Soak, or hold, the metal at a specific temperature for an allotted period of time. Cool the metal to room temperature.

Can you quench metals?

Not all metals should be quenched – quenching can crack or warp some metals. Generally, brine or water can rapidly cool metal, while oil mixtures are better for a slower cooling. The general guidelines are that you can use water to harden carbon steels, oil to harden alloy steels, and water to quench nonferrous metals.

How does grain orientation affect the rate of recrystallization?

The orientation of a grain and how the orientation changes during deformation influence the accumulation of stored energy and hence the rate of recrystallization. The mobility of the grain boundaries is influenced by their orientation and so some crystallographic textures will result in faster growth than others.

How does deformation affect critical temperature?

Deformation affects the critical temperature. Increasing the magnitude of prior deformation, or reducing the deformation temperature, will increase the stored energy and the number of potential nuclei. As a result, the recrystallization temperature will decrease with increasing deformation.

What is secondary recrystallization?

Secondary recrystallization occurs when a certain very small number of {110}<001> (Goss) grains grow selectively, about one in 106 primary grains, at the expense of many other primary recrystallized grains. This results in abnormal grain growth, which may be beneficial or detrimental for product material properties.

What is the process of replacing deformed grains with new deformed grains?

Recrystallization is a process by which deformed grains are replaced by a new set of defect-free grains that nucleate and grow until the original grains have been entirely consumed. Recrystallization is usually accompanied by a reduction in the strength and hardness of a material and a simultaneous increase in the ductility.

What happens if the nuclei are larger than the critical radius?

If the nuclei were larger than some critical radius then it would be thermodynamically stable and could start to grow. The main problem with this theory is that the stored energy due to dislocations is very low (0.1-1 Jm −3) while the energy of a grain boundary is quite high (~0.5Jm −2 ).

What is the influence of second phase?

Many alloys of industrial significance have some volume fraction of second phase particles, either as a result of impurities or from deliberate alloying additions. Depending on their size and distribution such particles may act to either encourage or retard recrystallization.

Is recrystallization a process?

A precise definition of recrystallization is difficult to state as the process is strongly related to several other processes, most notably recovery and grain growth. In some cases it is difficult to precisely define the point at which one process begins and another ends.

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