Treatment FAQ

what turns copper black at sewage treatment plant

by Dayna Stracke Published 3 years ago Updated 2 years ago

Dissolved metal removal is driven by pH of the solution or metal precipitants. In the case of dissolved copper ions, the traditional method for removal is to raise the pH of the wastewater with caustic soda or lime or soda ash. This creates an insoluble metal hydroxide.

Full Answer

What happens to the copper in a wastewater treatment plant?

Possible plant upgrades include: the addition of a sand filtration unit, the addition of a reverse osmosis or ion exchange system and the addition of a reactor for copper precipitation from the wastewater. In addition to these solutions, land application can be explored as an alternative to discharging into the Otter River.

What causes black sludge in wastewater treatment plant?

Feb 27, 2011 · In the case of dissolved copper ions, the traditional method for removal is to raise the pH of the wastewater with caustic soda or lime or soda ash. This creates an insoluble metal hydroxide. The metal hydroxide is water –loving ion that creates excessive and sometimes difficult to dewater sludge.

How do you get rid of dissolved copper in wastewater?

The Aeration tank succeeding an digestor turns black and the COD reduction efficiency is reduced when the feed is increased. the D.O is 1.5- 1.9 in the aeration tank. ... central wastewater ...

What is the hardness of copper in wastewater treatment?

Nov 03, 2016 · Northern Works sewage nightmare turns Jukskei black. ... that causes explosive plant and algae growth, in turn depleting oxygen and killing aquatic life – for decades. ... wastewater treatment ...

What is rod wire?

Rod is similar to wire in that it has a circular cross section but is more rigid. Rod and wire are used for screening, fasteners, jewelry, cotter pins, lock washers, springs, truss wire, wire brushes, welding rods, chains, hooks, and electrical conductors. Tubing is material in the form of long hollow cylinders.

What is a plate made of?

Plate is a wide rigid piece of metal usually greater than ¼ inch thick. Printing plates were often made from copper, as are plate heat exchangers and some chemical processing vessels.

What is the copper industry?

Copper Industry. The copper industry is a major contributor to the global economy. How to remove it from wastewater provides benefits to more than just the companies mining copper and fabricating products from it. Copper is an essential component in the motors, wiring, radiators, connectors, brakes, and bearings used in the automotive sector, ...

What is ventilataqua electrocoagulation?

VentilAQUA’s electrocoagulation technology considered in this case is a continuous flow system, composed by multi-stage cells, with multi-electrode, containing special electrodes of suitable material for the function of oxidation and coagulation, with modular configuration and special internal geometry for optimum efficiency, totally build in PE / PP.

All Answers (37)

The obvious answer for both color and odor is that the aeration is not sufficient... Maybe the aeration membranes (if those are used) need to be cleaned. There is a chance that some of the pores are clogged, resulting to large bubbles and worse oxygen transfer.

Similar questions and discussions

Why is the color of mixed liquor in activated sludge basins or aerobic sequencing batch reactors (SBR) cream or orange?

Why does hydrogen sulfide smell bad?

Lagoons. Hydrogen Sulfide makes your lagoons smell bad and your customers upset. It’s caused by the compact sludge forming anaerobic and septic conditions. Rotten egg odors and excess sludge in a lagoon.

What are the sources of sulfur?

Sulfur is present in human and livestock waste as organic sulfides, such as mercaptans and disulfides. It is also present in rainfall, primarily over metropolitans areas, but the most common source of sulfide is in domestic wastewater as sulfate. An industry can also generate sulfate/sulfide wastes that may contribute to sulfide levels in wastewater such as: 1 Sulfate- Seen in sea food processing or fermentation plants 2 Sulfide- Seen in tanneries and paper manufacturing 3 Sulfite 4 Thiosulfate 5 Decomposition of xanthates used in the mining industry (12).

What are the problems associated with hydrogen sulfide?

There are various problems associated with hydrogen sulfide generation, such as toxicity, noxious odors, and the generation of corrosive sulfuric acid. Sulfur is present in human and livestock waste as organic sulfides, such as mercaptans and disulfides. It is also present in rainfall, primarily over metropolitans areas, ...

Where is sulfide found?

It is also present in rainfall, primarily over metropolitans areas, but the most common source of sulfide is in domestic wastewater as sulfate. An industry can also generate sulfate/sulfide wastes that may contribute to sulfide levels in wastewater such as: Sulfate- Seen in sea food processing or fermentation plants.

What is the process of hydrogen sulfide?

The process of hydrogen sulfide generation depends on pH, temperature, and reactant concentrations (11). Hydrogen sulfide gas in the sewer atmosphere may be adsorbed in the thin film of water that normally covers the sewer walls and may be partially oxidized to sulfuric acid by bacteria of the genus Thiobacillus (8).

What is slime film?

The slime film creates an anaerobic environment that allows sulfide reducing bacteria (SRB) to thrive and they contribute to iron sulfide formation, which diminishes the protective oxide film on most stainless steels. Concrete – Concrete is a composite material made of sand, rock, and cement.

Is hydrogen sulfide toxic?

Hydrogen sulfide is a toxic concern for wastewater operators, especially if odor-masking agents are used, since it can affect the nervous system causing headaches, nausea, irritation of the skin, eyes, and respiratory tract, and at high doses it can cause death (2, 3).

What is sewage treatment plant?

A sewage treatment plant is designed to treat and process raw sewage over different steps involving breaking, filtering, settling, controlled aerobic decomposition and chemical treatment. One of the most common things that come in our mind regarding human waste; is to dump it to the sewers and let the government take care of it.

What is chemical sewage treatment?

The preliminary chamber is equipped with coarse and fine mesh of screen as filters to remove large solid particles from getting into the system. In many designs it stay set at the top of the primary chamber with flow measurement device recording and filtering waste water inlet at the same time.

Why is activated carbon added to sewage?

It get on to absorb all the organic molecules associated with the smell and distinct colour. In many design the activated carbon sets are filled just after the settling chamber; thus allowing waste water to be treated before moved to next chamber.

How long does it take for chlorine to kill bacteria?

This is done by adding a 5 % solution of chlorine to kill of bacteria within a period of 30 minutes. Further chemical treatment is done to remove the smell and get rid of the pale colour. The treated water is then either discharged to the sea, to shore facilities or used in toilets for flushing.

Where is raw water stored?

The raw waste water originating from toilet, wash basins and bathrooms; with a concentration of 0.1% solid waste by weight is stored in the primary chamber. The sewage is fed into the chamber with special macerator pumps that reduce human waste to slurry using blending and grinding techniques.

How does activated carbon work?

In many design the activated carbon sets are filled just after the settling chamber; thus allowing waste water to be treated before moved to next chamber. This is achieved by the process called adsorption. Many a times they not just used to remove odor and color; but also unwanted bi-product of biological treatment.

Where does waste water go after biological treatment?

The waste water after biological treatment went to the settling chamber where the heavier solid particles settles down by effect of gravity. To further support the process and nullify effects of flow of sewage; the waste water is inserted into the chamber from chamber and exit from top to the next chamber.

What Is The Copper Forming Industry?

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Copper forming plants roll, draw, extrude, and forge copper and copper alloys. In addition to these forming operations, there are surface cleaning and heat treatment processes which impart desired surface and physical properties to the metal. For the purposes of this regulation, copper alloys include any alloy in which copper is …
See more on epa.gov

Facilities Covered

  1. Manufacture of formed copper and copper alloy products
  2. Excluded:
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Related Categories

  1. Casting is regulated under the Metal Molding and Casting (Foundries) Category (40 CFR Part 464).
  2. The manufacture of copper powders and the forming of parts from copper or copper alloy powders is regulated under the Nonferrous Metals Forming and Metal Powders Category (40 CFR Part 471).
  1. Casting is regulated under the Metal Molding and Casting (Foundries) Category (40 CFR Part 464).
  2. The manufacture of copper powders and the forming of parts from copper or copper alloy powders is regulated under the Nonferrous Metals Forming and Metal Powders Category (40 CFR Part 471).
  3. Metal Finishing (40 CFR Part 433)
  4. Metal Products and Machinery (40 CFR Part 438)

Guidance Documents

Rulemaking History

  • 1986 Amendment
    1. Final Rule(March 5, 1986)
  • 1983 Initial Rulemaking
    1. Documents, including: 1.1. Final Rule (August 15, 1983) 1.2. Development Document (March 1984) Industry description, wastewater characterization, treatment technologies, regulatory compliance cost estimates and pollutant loadings for the final rule 1.3. Proposed Rule (Novemb…
See more on epa.gov

Additional Information

  • For additional information regarding Copper Forming Effluent Guidelines, please contact Samantha Lewis([email protected]) or 202-566-1058.
See more on epa.gov

Copper Industry

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The copper industry is a major contributor to the global economy. How to remove it from wastewater provides benefits to more than just the companies mining copper and fabricating products from it. Copper is an essential component in the motors, wiring, radiators, connectors, brakes, and bearings used in the automotive sector, …
See more on ventilaqua.com

The Technology

  • VentilAQUA’s electrocoagulation technology considered in this case is a continuous flow system, composed by multi-stage cells, with multi-electrode, containing special electrodes of suitable material for the function of oxidation and coagulation, with modular configuration and special internal geometry for optimum efficiency, totally build in PE / PP. This system also includes a sp…
See more on ventilaqua.com

The Copper Wastewater

  • The wastewaters to be treated are coming from a yarn production process that generates a current with a high concentration of copper. These wastewaters are characterized mainly by the presence of a copper content between 1.000 –5.000 mg/l and a very low pH around 1. It was tested also in a very high concentration of copper, 23.600 mg/l. The lab tes...
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Findings and Conclusions

  • The viability and efficiency of this technology to remove copper from this wastewater are proved. This means less operating costs and better efficiency results, as it shows above: 1. > 99.9% removal of copper 2. > 99.79% removal of Zinc 3. No coagulants needed 4. Low power cost, best results of 0.140 Watts per gram of copper removed 5. Improved sludge dehydration performanc…
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The Future of Wastewater Treatment

  • Downstream the electro-coagulation, we can add the traditional methods of sludge separation by settling or by flotation. The combination of the Dissolved Ozone Flotation and Electrocoagulation system will result in an extremely strong application to remove the most difficult molecules. We have several examples around the world either combining Dissolved Ozone Flotation and Electro…
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